Describe reactions of group (IV) elements with nitric acid

Describe reactions of group (IV) elements with nitric acid

Reactions of group (IV) elements with nitric acid

With concentrated nitric acid.

C, Si, Ge and Sn react to form dioxide

C(s) + 4HNO3(aq)→ CO2(g) +4NO2(g) + 2H2O(l)

Pb reacts to form lead II nitrate and nitrogen dioxide.

Pb(s) + 4HNO3(aq)  →  Pb(NO3)2(aq) + 2NO2(aq)+ 2H2O(l)

With 50% nitric acid.

Pb reacts to form lead II nitrate and nitrogen monoxide.

3Pb(s) + 8HNO3(aq)  → 3Pb(NO3)2(aq) + 2NO(aq)+ 4H2O(l)

 

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