Reaction of alkenes with hydrogen bromide in presence of a peroxide

Reaction of alkenes with hydrogen bromide in presence of a peroxide

Reaction of alkenes with hydrogen bromide in presence of a peroxide

In presence of a peroxide, alkenes react with HBr by free radial mechanisms; but in this case hydrogen atom goes a carbon atom that carry the leat number of a hydrogen atoms of those that form a double bond  otherwise the bromine atom goes to a carbon with the highest number of  hydrogen atoms.

Example 

Propene reacts with hydrogen bromide in presence of a peroxide to produce 1-bromopropane

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