Disadvantages of using potassium permanganate (VII) in volumetric analysis

Disadvantages of using potassium permanganate (VII) in volumetric analysis

Disadvantages of using potassium permanganate (VII) in volumetric analysis

  • Manganate (VII) cannot be used as a primary standard because
  • it cannot be obtained in pure form. The impurities are MnO2.
  •  Aqueous solutions of manganese (VII) is unstable and slowly deposit brown manganese (IV) oxide on standing.
  •  Hydrochloric acid cannot be used as an oxidizing agent of potassium permanganate VII
  •  Nitric acid cannot be used to oxidize potassium permanganate (VII) solution because it is an oxidizing agent

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