Enthalpy of ionization

Enthalpy of ionization

Enthalpy of ionization: refers to enthalpy change for conversion of gaseous atoms into free gaseous ions, e.g.

Na(g) → Na+(g)+ e  ∆HmӨ(298K) = +502kJmol-1

Factors affecting magnitude of ionization energy

  • Size of an atom: Small atoms have strong attraction to outer electrons leading to high ionization energy.
  • Electronegativity: highly electronegative atoms have high attraction to valence electron causing high ionization energy.
  • Electropositivity: highly electropositive atoms have low attraction to valence electrons leading low ionization energy.

 

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