Lattice enthalpy/energy

Lattice enthalpy/energy

Lattice enthalpy/energy

This is the name given to the enthalpy change for the reaction in which 1mole of crystalline solid is formed from its component ions in the gaseous phase.

Na+(g) + Cl(g) → NaCl(s)  ∆HmӨ(298K) = -788 kJmol-1

 Factors affecting the magnitude of lattice energy

  • Size of the ion; small ions have strong interionic attraction causing high lattice energy
  • Charge on the ions: ions with big charge have strong interionic attraction leading to high lattice energy.

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